Well yes: you can take your car to the ITV without having made a prior appointment. Note, not everywhere and not always. It depends on the specific station and the autonomous community where you are. So it's not guaranteed that they will attend to you. Better go prepared with the documentation and a good amount of patience.
Some stations only work by appointment. Others admit those who arrive without notice, but they place you after those who did reserve. This means you may wait much longer. The RACE organization reminds that availability varies depending on the day's workload. So don't be overconfident. Don't expect to arrive and be served immediately.
If you are a foreigner and have just bought a car or need to pass the ITV for the first time in Spain, this interests you, a lot. The Technical Vehicle Inspection is mandatory to drive. Without it, a sure fine. The best thing is to check beforehand the website of the station closest to you. Many have a section for 'without appointment' or 'emergencies'.
Another option: call by phone and ask directly. Don't just rely on what you read in forums – you know how that goes. Each autonomous community manages its own stations, and the rules change. For example, in Madrid some admit without an appointment; in Barcelona, not so much. So inform yourself well so you don't make the trip for nothing.
If you decide to go without an appointment, bring everything: registration certificate, technical specifications, valid insurance. And if your car is old or you know it has defects, better fix them beforehand. The ITV without an appointment is a resource, not a bargain. It saves you the step of requesting a turn, but not the technical requirements.
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